Mussels document loss of bioavailable polycyclic aromatic hydrocarbons and the return to baseline conditions for oiled shorelines in Prince William Sound, Alaska     

Page DS  Boehm PD  Brown JS  Neff JM  Burns WA  Bence AE 《Marine environmental research》2005,60(4):422-436

Polycyclic aromatic hydrocarbons (PAH) were measured in mussels (Mytilus trossulus) collected between 1990 and 2002 from 11 sites on the shores of Prince William Sound (PWS), Alaska, that were heavily oiled by the 1989 Exxon Valdez oil spill (EVOS). This study, utilizing the methods of the NOAA Status and Trends Mussel Watch Program, found that concentrations of PAH released from spill remnants have decreased dramatically with time and by 2002 were at or near the range of total PAH (TPAH) of 3-355 ng/g dry weight obtained for mussels from unoiled reference sites in PWS. Time-series TPAH data indicate a mean TPAH half-life in mussel tissues of 2.4 years with a range from 1.4 to 5.3, yielding an annual mean loss of bioaccumulated TPAH of 25%. The petroleum-derived TPAH fraction in mussel tissues has decreased with time, reflecting the decreasing release of EVOS residues in shoreline sediments. These results show that PAH from EVOS residues that remain buried in shoreline sediments after the early 1990s are in a form and at locations that have a low accessibility to mussels living in the intertidal zone.  相似文献   

The sea-surface microlayer of puget sound: Part I. Toxic effects on fish eggs and larvae     

John Hardy  Steven Kiesser  Liam Antrim  Alan Stubin  Richard Kocan  John Strand 《Marine environmental research》1987,23(4)

The sea surface is an important habitat for the developmental stages (eggs and larvae) of many fish and invertebrates; it is also a concentration point for anthropogenic contaminants entering the sea. Studies were conducted to determine the extent to which the sea surface of Puget Sound was toxic to the early life history stages of fish. Three urban bays with suspected contamination, a rural reference bay, and a Central Sound site were compared. Surface-dwelling eggs and organisms (zooneuston) were collected with a surface-skimming neuston net and their densities enumerated. Sand sole (Psettichthys melanostictus) embryos were exposed in the field and laboratory to the sea-surface microlayer. To develop a useful year-round approach to monitoring sea-surface toxicity, larval development of anchovies, kelp bass, and sea urchins was also evaluated as an indication of sea-surface microlayer toxicity.During the spawning season (February and March), urban boys in Puget Sound had lower concentrations of sand sole eggs and neustonic organisms on the sea surface than did the rural bayor Central Sound reference sites. Compared to the reference sites, laboratory exposure to surface microlayer samples collected from urban bay sites generally resulted in more chromsomal aberrations in developing sole embryos, reduced hatching success of sole larvae, and reduced growth in trout cell cultures. In situ hatching success of sole eggs was reduced by half or more in urban bays compared to reference sites.Toxicity was associated with visible surface slicks and, in urban bays, increased with increasing surface pressure (dynes cm⁻¹). Results to be reported separately (Part II) indicate that toxicity is strongly correlated with the presence of high concentrations of polycyclic aromatic hydrocarbons and metals in the sea-surface microlayer. The toxicity of SMIC samples was similar when evaluated by sole, anchovy, kelp bass, or sea urchin tests. A sea-surface monitoring program could use sea urchin embryos to evaluate site-specific sea-surface toxicity throughout the year.  相似文献   

Concentrations of suspended matter and particulate cadmium,copper, lead and zinc in the Indian sector of the antarctic ocean   总被引：1，自引：0，他引：1  

John E. Harris  Gastone J. Fabris 《Marine Chemistry》1979,8(2):163-179

The concentrations of suspended matter and particulate Cd, Cu, Pb and Zn were determined for 36 samples collected at 6 stations in the Antarctic Ocean during December, 1970 and January, 1971 using membrane filters. The concentration of suspended matter was determined gravimetrically and trace metal levels were determined using anodic stripping voltammetry. For waters deeper than 100 m the concentration of suspended matter was < 100 μg l^?1. Concentrations up to 542 μg l^?1 were recorded between surface and 100 m. Individual concentrations of the metals were scattered with depth. Average concentrations of particulate metals were: Cd, 3.5 ng l^?1; Cu, 100 ng l^?1; Pb, 35 ng l^?1; and Zn, 230 ng ;l^?1 These measurements represent non-steady state conditions of early Antarctic summer as the ice pack disintegrates and biological activity increases.  相似文献   

An experimental facility for testing loaded structures in a high hydrostatic pressure environment and an application to axially loaded columns     

Richard P. Shaw  John Sezna 《Ocean Engineering》1971

An experimental facility is described for the testing of structures under a combined axial load and hydrostatic pressure load. This facility was used to determine the effects of hydrostatic pressure (up to 6000 psi) on the load-carrying capacity of slender metal columns. There appeared to be no significant effect in this case.  相似文献   

Maternal transfer of bioactive polychlorinated aromatic hydrocarbons in spawning chinook salmon (Oncorhynchus tschawytscha)     

Gerald T. Ankley  Donald E. Tillitt  John P. Giesy 《Marine environmental research》1989,28(1-4)

The biological potency (relative to 2,3,7,8-tetrachlorodibenzo-p-dioxin. TCDD) of planar polychlorinated aromatic hydrocarbons (PCHs) in extracts of eggs and flesh from spawning female chinook salmon (Oncorhynchus tschawytscha) from Lake Michigan was determined by measuring the induction of 7-ethoxyresorufin O-deethylase activity in H-4-II-E rat hepatoma cells. TCDD-equivalents in flesh and egg samples ranged from 0 to 115·8 pg/g, and were approximately 5-fold greater in eggs than in flesh. These results suggest that the maternal transfer of PCHs may play a role in determining the reproductive success of Lake Michigan chinook salmon.  相似文献   

Transient soil response in a porous seabed with variable permeability     

Brian R. Seymour  Dong S. Jeng  John R.C. Hsu 《Ocean Engineering》1996,23(1):27-46

The soil permeability of many natural marine sediments decreases with depth because of consolidation under overburden pressure. This is accompanied by a decrease in porosity and void ratio that also affect the permeability. Conventional theories for wave-induced soil response have assumed a homogeneous porous seabed. This paper presents a new approach for the wave-induced response in a soil matrix, with variable permeability as a function of burial depth. The soil matrix considered is unsaturated and anisotropic, and is subject to a three-dimensional wave system. The pore pressure and effective stresses induced by such a system are obtained from a set of equations incorporating a variable permeability. Verification is available through reduction to the simple case of uniform permeability. The results indicate that the effect of variable soil permeability on pore pressure and vertical effective stress may be significant, especially in a gravelled seabed and for unsaturated sandy soils.  相似文献   

Government response to marine pollution from ships     

John Bywater  Commander 《Marine Policy》1995,19(6)

The Marine Pollution Control Unit (MPCU) is the competent national authority for discharging the Secretary of State for Transport responsibility for pollution from ships under the Prevention of Oil Pollution Act 1971 and subsequent legislation covering other hazardous substances. It is an integral part of The Coastguard Agency, an executive agency of The Department of Transport. MPCU is responsible for maintaining the National Contingency Plan, for monitoring and assessing all pollution incidents within UK waters including dealing with pollution from ships and for advising on/co-ordinating shoreline counter pollution operations, and for fostering and maintaining international relationships for mutual support.  相似文献   

CO₂ cycling in the coastal ocean. I – A numerical analysis of the southeastern Bering Sea with applications to the Chukchi Sea and the northern Gulf of Mexico     

John J. Walsh  Dwight A. Dieterle 《Progress in Oceanography》1994,34(4)

A quasi-two dimensional model of the carbon and nitrogen cycling above the 70m isobath of the southeastern Bering Sea at 57°N replicates the observed seasonal cycles of nitrate, ammonium, ΣCO₂, pCO₂, light penetration, chlorophyll, phytoplankton growth rate, and primary production, as constrained by changes in wind, incident radiation, temperature, ice cover, vertical and lateral mixing, grazing stress, benthic processing of phytodetritus and zooplankton fecal pellets, and the pelagic microbial loop of DOC, bacteria, and their predators. About half of the seasonal resupply of nitrate stocks to their initial winter conditions is derived from in situ nitrification, with the rest obtained from deep-sea influxes. Under the present conditions of atmospheric forcing, shelf-break exchange, and food web structure, this shelf ecosystem serves as a sink for atmospheric CO₂, with storage in the forms of exported DOC, DIC, and unutilized POC (phytoplankton, bacteria, and fecal pellets).As a consequence of just the rising levels of atmospheric pCO₂ since the the Industrial Revolution, however, the biophysical CO₂ status of the Southeastern Bering Sea shelf may have switched over the last 250 years, from a prior source to the present sink, since this relatively pristine ecosystem has unergone little eutrophication. Such fluctuations of CO₂ status may thus be reversed by the physical processes of : (1) reduction of atmospheric pCO₂, (2) increased on welling of deep-sea ΣCO₂, and (3) warming of shelf waters. Based on our application of this model to the Chukchi Sea and the Gulf of Mexico, about 1.0–1.2 gigatons C y^-1 of atmospheric CO₂ may now be sequestered by temperate and polar shelf ecosystems. When tropical systems are included, however, a positive net sink of only 0.6–0.8. × 10¹⁵g C y⁻¹ may prevail over all shelves.  相似文献   

Threshold of motion of coarse-grained sediment under waves in shallow water   总被引：1，自引：0，他引：1  

John C. Morfett   《Coastal Engineering》1992,18(3-4)

This paper considers the threshold of motion of sediment in shallow coastal waters under breaking and non-breaking waves. A simple model, representing conditions at the fluid/sediment interface, is developed. The representation of a breaking wave is based on bore theory, and the shear stress at the bed is based on the friction formula of O'Connor and Yoo. A threshold formula is presented based on the use of energy dissipation. The threshold data is also related to the Shields threshold criterion.  相似文献   

The distribution of tritium and CFCs in the Weddell Sea during the mid-1980s     

Manfred Mensch  Reinhold Bayer  John L. Bullister  Peter Schlosser  Ray F. Weiss 《Progress in Oceanography》1996,38(4):377-388

Transient tracer data (tritium, CFC11 and CFC12) from the southern, central and northwestern Weddell Sea collected during Polarstern cruises ANT III-3, ANT V-2/3/4 and during Andenes cruise NARE 85 are presented and discussed in the context of hydrographic observations. A kinematic, time-dependent, multi-box model is used to estimate mean residence times and formation rates of several water masses observed in the Weddell Sea.Ice Shelf Water is marked by higher tritium and lower CFC concentrations compared to surface waters. The tracer signature of Ice Shelf Water can only be explained by assuming that its source water mass, Western Shelf Water, has characteristics different from those of surface waters. Using the transient nature of tritium and the CFCs, the mean residence time of Western Shelf Water on the shelf is estimated to be approximately 5 years. Ice Shelf Water is renewed on a time scale of about 14 years from Western Shelf Water by interaction of this water mass with glacial ice underneath the Filchner-Ronne Ice shelf. The Ice Shelf Water signature can be traced across the sill of the Filchner Depression and down the continental slope of the southern Weddell Sea. On the continental slope, new Weddell Sea Bottom Water is formed by entrainment of Weddell Deep Water and Weddell Sea Deep Water into the Ice Shelf Water plume. In the northwestern Weddell Sea, new Weddell Sea Bottom Water is observed in two narrow, deep boundary currents flowing along the base of the continental slope. Classically defined Weddell Sea Bottom Water (θ ≤ −0.7°C) and Weddell Sea Deep Water (−0.7°C ≤ θ ≤ 0°C) are ventilated from the deeper of these boundary currents by lateral spreading and mixing. Model-based estimates yield a total formation rate of 3.5Sv for new Weddell Sea Bottom Water (θ = −1.0°C) and a formation rate of at least 11Sv for Antarctic Bottom Water (θ = −0.5°C).  相似文献